机械剪切剥离法制备石墨烯研究进展

doi:10.16180/j.cnki.issn1007-7820.2020.12.009

摘要/Abstract

摘要：

石墨烯优异的电学、光学和力学性能掀起了多领域的研究热潮,其制备方法也成为重点研究方向。机械剪切剥离法成本低,操作简单,且不会破坏石墨烯本征特性等特性,备受研究者关注。文中介绍了石墨烯的性质和剥离机理,并阐述了机械剥离法中低能纯剪法、三辊磨剥法和球磨法,比较了各方法的特点及面临的问题。由于球磨法是目前最有望大规模制造石墨烯的方法,故文中优化了球磨工艺,提出了一种磨盘式结构球磨机。该球磨机有效避免了磨球之间的撞击力,保护石墨晶格免于破环,提高了剪切效率。

关键词: 石墨烯, 剥离机理, 剪切, 机械剥离制备, 球磨设备, 磨盘式研磨

Abstract:

The excellent electrical, optical and mechanical properties of graphene have set off a research boom in various fields, and its preparation method has become the focus of research. Mechanical shear stripping method has attracted much attention because of its low cost, simple operation, and no damage to the intrinsic properties of graphene. This paper introduces the properties and stripping mechanism of graphene, and reviewes the low energy pure shearing method, the three-stick grinding and stripping method and the ball milling method in the mechanical peeling method, and compares their respective characteristics and problems. Since the ball milling method is currently the most promising method for producing graphene on a large scale. the ball milling process is optimized in this paper, and a grinding disc structure ball mill is proposed. The ball mill effectively avoids the impact force between the grinding balls, protects the graphite lattice from being broken, and improves the shearing efficiency.

Key words: graphene, peeling mechanism, shear, mechanical stripping preparation, ball mill equipment, grinding disc grinding

中图分类号:

TN04

王家涛,魏镜弢,钱杰,吴张永,王庭有. 机械剪切剥离法制备石墨烯研究进展[J]. 电子科技, 2020, 33(12): 44-48.

WANG Jiatao,WEI Jingtao,QIAN Jie,WU Zhangyong,WANG Tingyou. Research Progress in Preparation of Graphene by Mechanical Shear Stripping[J]. Electronic Science and Technology, 2020, 33(12): 44-48.

图/表 2

参考文献 36

[1]	张宇辉. 基于分子结构力学的石墨烯力学特性研究[D]. 西安:西安建筑科技大学, 2016.
	Zhang Yuhui. Mechanical property of single layer graphene based on the molecular structural mechanics method[D]. Xi’an:Xi’an University of Architecture and Technology, 2016.
[2]	刘霞. 石墨烯及其复合材料的制备与性能研究[D]. 上海:东华大学, 2016.
	Liu Xia. Preparation and properties of graphene based ceramics[D]. Shanghai:Donghua University, 2016.
[3]	Mende S, Stenger F, Peukert W, et al. Mechanical production and stabilization of submicron particles in stirred media mills[J]. Powder Technology, 2003,132(1):64-73 doi: 10.1016/S0032-5910(03)00042-1
[4]	刘硕, 廖庆亮, 丁一, 等. 石墨烯材料的制备及性能研究[J]. 新材料产业, 2016(10):37-42.
	Liu Shuo, Liao Qingliang, Ding Yi, et al. Preparation and properties of graphene materials[J]. Advanced Materials Industry, 2016(10):37-42.
[5]	晏伯武. 石墨烯的制备和性能研究[J]. 中国陶瓷, 2017,53(9):6-10.
	Yan Bowu. Preparation and properties of graphene[J]. China Ceramics, 2017,53(9):6-10.
[6]	王振廷, 戴东言, 李洋, 等. 石墨烯的机械剥离法制备及表征[J]. 黑龙江科技大学学报, 2018,28(2):200-203.
	Wang Zhenting, Dai Dongyan, Li Yang, et al. Graphene preparation by mechanical exfoliation and its characterization[J]. Journal of Heilongjiang University of Science & Technology, 2018,28(2):200-203.
[7]	王玉姣, 田明伟, 曲丽君. 石墨烯的研究现状与发展趋势[J]. 成都纺织高等专科学校学报, 2016,33(1):1-18.
	Wang Yujiao, Tian Mingwei, Qu Lijun, et al. Research status and development trend of graphene[J]. Journal of Chengdu Textile College, 2016,33(1):1-18.
[8]	李一恒. 石墨烯初探之一——石墨烯及其机械剥离法制备[J]. 化学工程与装备, 2014(10):38-40,44.
	Li Yiheng. One of the preliminary studies of graphene-graphene and its mechanical stripping method[J]. Chemical Engineering & Equipment, 2014(10):38-40,44.
[9]	赵剑, 蒋中山. 石墨烯的制备及应用发展方向概述[J]. 当代化工, 2017,46(10):2119-2123,2127.
	Zhao Jian, Jiang Zhongshan. Research progress in preparation and application of graphene[J]. Contemporary Chemical Industry, 2017,46(10):2119-2123,2127.
[10]	Geim A K, Novoselov K S. The rise of graphene[J]. Nature Materials, 2007,6(3):183-191. pmid: 17330084
[11]	Geim A K. Graphene: status and prospects[J]. Science, 2009,324(5934):1530-1534. doi: 10.1126/science.1158877 pmid: 19541989
[12]	Zhu Y, Murali S, Cai W, et al. Graphene and graphene oxide: synjournal,properties, and applications[J]. Cheminform, 2010,22(46):3906-3924.
[13]	Hou Y, Cui X, Zhang C, et al. Liquid-phase exfoliation,functionalization and applications of graphene[J]. Nanoscale, 2011,3(5):18-26.
[14]	陈金凤. 石墨烯的连续机械剥离制备及其复合材料的性能研究[D]. 厦门:华侨大学, 2013.
	Chen Jinfeng. Studies on continuous mechanical exfoliation of graphene via three-roll mill and the properties of nanocomposites[D]. Xiamen:Huaqiao University, 2013.
[15]	江莞, 范宇驰, 刘霞, 等. 机械剥离法制备石墨烯及其在石墨烯/陶瓷复合材料制备中的应用[J]. 中国材料进展, 2011,30(1):12-20,26.
	Jiang Wan, Fan Yuchi, Liu Xia, et al. Preparation of graphene by mechanical exfoliation and its application in preparation of graphene/ceramic composites[J]. Materials China, 2011,30(1):12-20,26.
[16]	Chen J, Duan M, Chen G. Continuous mechanical exfoliation of graphene sheets via three-roll mill I[J]. Journal of Materials Chemistry, 2012,22(37):19625-19633. doi: 10.1039/c2jm33740a
[17]	陈庆, 孙丽枝, 曾军堂. 机械法剪切剥离制备石墨烯的研究现状和发展趋势[J]. 新材料产业, 2016(10):43-47.
	Chen Qing, Sun Lizhi, Cen Juntang. Research status and development trend of mechanically processed shear stripping to prepare graphene[J]. Advanced Materials Industry, 2016(10):43-47.
[18]	Antisari M V, Montone A, Jovic N, et al. Low energy pure shear milling: A method for the preparation of graphite nano-sheets[J]. Scripta Materialia, 2006,55(11):1047-1050. doi: 10.1016/j.scriptamat.2006.08.002
[19]	Duan M, Chen J, Chen G. Continuous mechanical exfoliation of graphene sheets via three-roll mill II[J]. Journal of Materials Chemistry, 2013,23(4):331-339.
[20]	方景光. 粉磨工艺及设备[M]. 武汉: 武汉理工大学出版社, 2002.
	Fang Jinguang. Grinding process and equipment[M]. Wuhan: Wuhan University of Technology Press, 2002.
[21]	Zhao W F, Wu F R, Wu H, et al. Preparation of colloidal dispersions of graphene sheets in organic solvents by using ball milling[J]. Journal of Nanomaterials, 2010,3(699):1-5
[22]	Wu H, Zhao W F, Hu H W, et al. One-step in situ ball milling synjournal of polymer-functionalized graphene nanocomposites[J]. Journal of Materials Chemistry, 2011,21(24):8626-8632. doi: 10.1039/c1jm10819k
[23]	Wu H, Zhao W F, Chen G H. One‐pot in situ ball milling preparation of polymerr/graphene nanocomposites[J]. Journal of Applied Polymer Science, 2012,125(5):458-465.
[24]	Fan Y C, Wang L J, Li J L, et al. Preparation and electrical properties of graphene nanosheet/Al₂O₃ composites[J]. Carbon, 2010,48(6):1253-1259.
[25]	León V. Few-layer graphenes from ball-milling of graphite with melamine[J]. Chemical Communications (Cambridge, England), 2011,47(39):2134-2140. doi: 10.1039/C0CC04926C
[26]	Jeon I Y, Shin Y R, Sohn G J, et al. Edge-carboxylated graphene nanosheets via ball milling[J]. Proceedings of the National Academy of Sciences of the United States of America, 2012,109(15):4564-4569.
[27]	Jeon I Y, Shin Y R, Sohn G J, et al. BaekEdge-carboxylated graphene nanosheets via ball milling proc[J]. Proceedings of the National Academy of Sciences of the United States of America, 2012,109(15):5588-5593. doi: 10.1073/pnas.1116897109 pmid: 22454492
[28]	Jeon I Y, Choi H J, Jung S M, et al. Large-scale production of edge-selectively functionalized graphene nanoplatelets via ball milling and their use as metal-free electrocatalysts for oxygen reduction reaction[J]. Journal of the American Chemical Society, 2012,135(4):1386-1393. doi: 10.1021/ja3091643 pmid: 23110522
[29]	Jeon I Y, Choi M, Choi H J, et al. Antimony-doped graphene nanoplatelets Nat.Commun[J]. Journal of the American Chemical Society, 2015,6(1):1556-1564.
[30]	Jeon I Y, Zhang S, Zhang H J, et al. Edge-selectively sulfurized graphene nanoplatelets as efficient metal-free electrocatalysts for oxygen reduction reaction: the electron spin effect[J]. Advanced Materials, 2013,25(42):6138-6145. doi: 10.1002/adma.201302753 pmid: 24038522
[31]	Jeon I Y, Choi H J, Choi M, et al. Facile scalable synjournal of edge-halogenated graphene nanoplatelets as efficient metal-free eletrocatalysts for oxygen reduction reaction[J], Scientific Reports, 2013,3(1):6544-6552.
[32]	Jeon I Y, Bae S Y, Seo J M, et al. Scalable production of edge-functionalized graphene nanoplatelets via mechanochemical ball-milling[J]. Advanced Functional Materials, 2015,25(45):6961-6975. doi: 10.1002/adfm.201502214
[33]	Jeon I Y, Shin S H, Choi H J, et al. Heavily aluminated graphene nanoplatelets as an efficient flame-retardant[J]. Carbon, 2017,116(4):1386-1393.
[34]	Jeon I Y, Noh H J, Baek J B. Direct and efficient conversion from low-quality graphite to high-quality graphene nanoplatelets[J]. FlatChem, 2018,6(1):1556-1564.
[35]	AparnaR, Sivakumar N, Balakrishnan A, et al. An effective route to produce few-layer graphene using combinatorial ball milling and strong aqueous exfoliants[J]. Journal of Renewable and Sustainable Energy, 2013,5(3):033123. doi: 10.1063/1.4809794
[36]	干路平, 程起林, 顾达. 石墨超细片状磨碎的机理及方法[J]. 化工生产与技术, 1999(2):28-30,34.
	Gan Luping, Chen Qiling, Gu Da. Mechanism and method of graphite ultrafine flake grinding[J]. Chemical Rpoduction and Technolog, 1999(2):28-30,34.